Crystal structure of poly[(μ<sub>6</sub>-benzene-1,3,5-tricarboxylato)tris(1-methylpyrrolidin-2-one)nitratodizinc(II)]
نویسندگان
چکیده
The asymmetric unit of the title compound, [Zn 2 (C 9 H 3 O 6 )(NO )(C 5 NO) ] n , I consists two different zinc(II) ions bridged by carboxylate group benzene-1,3,5-tricarboxylate (BTC 3− ). Zn1 center is tetra-coordinated atoms three symmetrically equivalent BTC anions and one nitrate atom in a distorted tetrahedral geometry with Zn—O bond lengths (average value 1.958 Å) slightly shorter than distance [2.013 (6) Å]. Zn2 hexa-coordinated from carboxylic groups linkers 1-methylpyrrolidin-2-one (NMP) octahedral nearly values 2.091 2.088 Å, respectively). Linking paddle-wheel dizinc building units molecule results formation three-dimensional coordination framework.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E: Crystallographic Communications
سال: 2022
ISSN: ['2056-9890']
DOI: https://doi.org/10.1107/s2056989022011045